Ethylenediaminetetraacetate functionalized MgFe layered double hydroxide/biochar composites for highly efficient adsorptive removal of lead ions from aqueous solutions

by M. T. Amin, A. A. Alazba, M. Shafiq

The application of layered double hydroxides (LDHs) of MgFe and its composites with biochar of Eucalyptus camdulensis (Eb) and ethylenediaminetetraacetic acid (EDTA) was explored in a batch study to mitigate toxic lead ions (Pb²⁺) from synthetic wastewater solutions. SEM images revealed that MgFe/LDH composites with Eb were successfully formed, while FTIR spectra confirmed the successful adsorption of Pb²⁺ onto the MgFe/LDH and composite adsorbents. Batch equilibrium was attained after 60 min, then the adsorption capacity gradually increased. An increase in adsorption capacity (and a 60% decrease in the percentage removal) was observed by increasing the initial Pb²⁺ concentration, and the highest value was 136 mg g^-1 for MgFe/LDH-Eb_EDTA. A 50–60% increase in both the adsorption capacities and percent removal was seen in the pH range of 2–6. The second-order kinetic model had a nearly perfect fitting, suggesting that chemisorption was the mechanism controlling adsorption. The Langmuir isotherm model best presented the adsorption data, suggesting that the Pb²⁺ adsorption was monolayer, and predicted a better affinity between the adsorbent surface and absorbed Pb²⁺ for MgFe/LDH-Eb_EDTA in comparison to the other two adsorbents. The D–R isotherm suggested that the adsorption system was physical based on E values for all three adsorbents, while the Temkin isotherm model suggested that Pb²⁺ adsorption was heterogeneous. Finally, the Sips and R–P isotherms predicted that the adsorption of Pb²⁺ on the surface of the adsorbents was homogeneous and heterogeneous.